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21.
Wireless Personal Communications - Current mobile communications technology relies heavily on efficient design of antennas, where the operational characteristics of the wireless communication... 相似文献
22.
研究了镍基高温合金GH202在800~1100 ℃高温氧化后晶粒、碳化物和强化相的演变过程。采用透射电子显微镜、扫描电子显微镜和电子背散射衍射对其微观结构进行了表征。结果表明:镍基高温合金的硬度随氧化温度的升高而降低,1100 ℃氧化100 h后,硬度降低了43.5%。800和900 ℃氧化后晶粒生长速度较慢,而经900 ℃氧化后晶界碳化物析出显著增加。在1000和1100 ℃氧化后,晶粒尺寸明显增大。氧化过程中晶界迁移是由晶界两侧自由能差决定,温度越高,晶界向曲率中心迁移越快,大量细小晶粒被吞并形成了大晶粒。大块状碳化物(MC)分解成大量的碳原子,与Cr原子结合形成少量的富Cr颗粒状M23C6。在900 ℃氧化150 h后,M23C6演化为富Ti的M6C。随着氧化温度的升高,碳化物在γ相中回熔。在800、900和1000 ℃氧化后,γ′相逐渐长大,在1100 ℃氧化100 h后,完全溶解于γ相。 相似文献
23.
Prof. Dr. Chun-Chi Chen Prof. Dr. Jian Min Dr. Lilan Zhang Dr. Yu Yang Prof. Dr. Xuejing Yu Prof. Dr. Rey-Ting Guo 《Chembiochem : a European journal of chemical biology》2021,22(8):1317-1328
Cytochrome P450s are heme-thiolate enzymes that participate in carbon source assimilation, natural compound biosynthesis and xenobiotic metabolism in all kingdoms of life. P450s can catalyze various reactions by using a wide range of organic compounds, thus exhibiting great potential in biotechnological applications. The catalytic reactions of P450s are driven by electron equivalents that are sourced from pyridine nucleotides and delivered by cognate or matching redox partners (RPs). The electron transfer (ET) route from RPs to P450s involves one or more redox center-containing domains. As the rate of ET is one of the main determinants of P450 efficacy, an in-depth understanding of the P450 ET pathway should increase our knowledge of these important enzymes and benefit their further applications. Here, the various P450 RP systems along with current understanding of their ET routes will be reviewed. Notably, state-of-the-art structural studies of the two main types of self-sufficient P450 will also be summarized. 相似文献
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Han Chen Shunzo Shimai Jin Zhao Xiaojian Mao Jian Zhang Guohong Zhou Shiwei Wang 《Journal of the European Ceramic Society》2021,41(6):3838-3843
Alumina platelets were arranged horizontally in submicron alumina particles by shear force in the flow of slurries during casting. The obtained alumina green bodies with platelets were pressureless-sintered in vacuum, producing ceramics with thoroughly oriented grains and high transmittance. The effects of sintering parameters on the densification, microstructure evolution, and orientation degree of alumina ceramics were investigated and discussed. The results showed that the densification, grain size, orientation degree, and in-line transmittance were increased with increasing sintering temperature. The enhancement of orientation degree was mainly coherent with grain growth. The grain-oriented samples exhibited a much higher in-line transmittance (at 600 nm) of 61 % than that of the grain random sample (29 %). Moreover, the transmission remained a high level in the ultraviolet range (<300 nm). 相似文献
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Red’kina G. V. Sergienko A. S. Kuznetsov Yu. I. 《Protection of Metals and Physical Chemistry of Surfaces》2021,57(7):1352-1360
Protection of Metals and Physical Chemistry of Surfaces - Abstract—The ability of improving the protective properties of layers formed on zinc in the presence of sodium dodecylphosphonate... 相似文献
29.
Zhiwei Qiao Lifeng Li Shuhua Li Hong Liang Jian Zhou Randall Q. Snurr 《American Institute of Chemical Engineers》2021,67(10):e17352
Computational screening was employed to calculate the enantioseparation capabilities of 45 functionalized homochiral metal–organic frameworks (FHMOFs), and machine learning (ML) and molecular fingerprint (MF) techniques were used to find new FHMOFs with high performance. With increasing temperature, the enantioselectivities for (R,S)-1,3-dimethyl-1,2-propadiene are improved. The “glove effect” in the chiral pockets was proposed to explain the correlations between the steric effect of functional groups and performance of FHMOFs. Moreover, the neighborhood component analysis and RDKit/MACCS MFs show the highest predictive effect on enantioselectivities among the four ML classification algorithms with nine MFs that were tested. Based on the importance of MF, 85 new FHMOFs were designed, and a newly designed FHMOF, NO2-NHOH-FHMOF, with high similarity to the optimal MFs achieved improved chiral separation performance, with enantioselectivities of 85%. The design principles and new chiral pockets obtained by ML and MFs could facilitate the development of new materials for chiral separation. 相似文献
30.
在桥梁工程安全设计中,研究桥梁高桩承台基础抗震延性具有十分重要的意义.对高桩承台基础进行相似性分析并基于拟静力试验建立高桩承台基础拟试验样件,基于线弹性基础条件针对结构法向应力和试验件反应位移进行无量纲分析,确定研究对象和试验样件按8∶1缩小比例.通过较为严密的试验件加工工艺有效降低了试验测试误差.试验结果表明,基于拟静力试验的高桩承台基础可提高桥梁高桩承台基础抗震延性,并降低工程检测成本. 相似文献